SAFETY DATASHEET
SENGUARD®
REV. 05 – 06/2022
PRINT DATE – JUNE 2022
According to COMMISSION REGULATION (EU) 2020/878
Note on the translation: An automatic machine translation of this document is made possible in this page, while a human translation is prepared. Use the contact form if you wish to receive a human translation of this document.
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product Name:
SENGUARD®
Product Code:
1040
UFI Code:
G2N2-60J0-P00A-FXJF
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant uses:
Anti-stain treatment for stone surfaces.
Uses advised against:
All uses not specified in this section or in Section 7.3.
1.3 Details of the supplier of the safety data sheet
Supplier:
Cosentino Global S.L.U.,
Ctra. A334, Baza-Huércal Overa, km 59
04850 Cantoria (Almería) – Spain
Phone: +34 950 444 175 – Fax: +34 950 444 226
E-mail: info@cosentino.com
Website: www.cosentino.com
1.4 Emergency telephone number
ChemTel Inc. (24/7/365, multilingual):
Worldwide: +1-813-248-0585
United States: 1-800-255-3924 (free toll)
Australia: 1-300-954-583
China: 400-120-0751
India: 000-800-100-4086
Mexico: 01-800-099-0731
Brazil: 0-800-591-6042
For information on emergency phone numbers of EU national authorities you may check:
SECTION 2. Hazards identification
2.1 Classification of the substance or mixture
In accordance with Regulation (EU) No 1272/2008:
Eye Irrit. 2: Causes serious eye irritation.
Flam. Liq. 2: Highly flammable liquid and vapour.
STOT SE 3: May cause drowsiness or dizziness.
Skin Irrit. 2: Causes skin irritation.
2.2 Label elements
Labelling in accordance with Regulation (EU) No 1272/2008
Pictograms:
Signal word:
Danger
Hazard statements:
H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H319 – Causes serious eye irritation.
H336 – May cause drowsiness or dizziness.
Precautionary statements:
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P243: Take precautionary measures against static discharge.
P271: Use only outdoors or in a well-ventilated area.
P501: Dispose of contents and/or container according to the regulations for hazardous waste.
P403+P235: Store in a well-ventilated area. Keep cool.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
Contains:
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL, N-BUTYL ACETATE.
2.3 Other hazards
In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment.
SECTION 3. Composition/information on ingredients
3.1 Substances
Not applicable.
3.2 Mixtures
Substances posing a danger to health or the environment in accordance with the Regulation (EC) No 1272/2008, assigned a Community exposure limit in the workplace, and classified as PBT/vPvB or included in the Candidate List:
IDENTIFICATION |
CHEMICAL NAME/CLASSIFICATION(*) |
CONCENTRATION |
||
CAS: |
64-17-5 |
ETHANOL, ETHYL ALCOHOL(1) |
>= 25 % – < 50 % |
|
EC: |
200-578-6 |
Regulation 1272/2008 |
Flam. Liq. 2: H225 |
|
Index: |
603-002-00-5 |
|||
REACH: |
01-2119457610-43-XXXX |
|||
CAS: |
2031-67-6 |
TRIETHOXI(METHYL)SILANE |
>= 10 % – < 25 % |
|
EC: |
– |
Regulation 1272/2008 |
Flam. Liq. 1: H224 |
|
Index: |
– |
|||
REACH: |
– |
|||
CAS: |
123-86-4 |
N-BUTYL ACETATE(1) |
>= 10 % – < 25 % |
|
EC: |
204-658-1 |
Regulation 1272/2008 |
Flam. Liq. 3: H226; STOT SE 3: H336; EUH066 |
|
Index: |
607-025-00-1 |
|||
REACH: |
01-2119485493-29-XXXX |
|||
CAS: |
2943-75-1 |
TRIETHOXYOCTYLSILANE |
>= 10 % – < 25 % |
|
EC: |
220-941-2 |
Regulation 1272/2008 |
Skin Irrit. 2: H315 |
|
Index: |
– |
|||
REACH: |
– |
|||
CAS: |
67-63-0 |
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL(1) |
> 2.5 % – <= 10 % |
|
EC: |
200-661-7 |
Regulation 1272/2008 |
Eye Irrit. 2: H319; Flam. Liq. 2: H225; STOT SE 3: H336 |
|
Index: |
603-117-00-0 |
|||
REACH: |
01-2119457558-25-XXXX |
(*) The complete text of the H phrases is given in Section 16 of this Safety Datasheet
(1) Substance with a Community workplace exposure limit (see Section 8.1)
SECTION 4. First aid measures
4.1 Description of first aid measures
In case of doubt or when symptoms of feeling unwell persist, get medical attention. Never administer anything orally to persons who are unconscious.
Inhalation:
If breathing is irregular or stops, perform artificial respiration. Do not administer anything orally. If unconscious, place them in a suitable position and seek medical assistance.
Eye contact:
If wearing contact lenses, remove them. Wash eyes with plenty of clean and cool water for at least 10 minutes while pulling eyelids up, and seek medical assistance.
Skin contact:
Remove contaminated clothing. Wash skin vigorously with water and soap or a suitable skin cleaner. NEVER use solvents or thinners.
Ingestion:
If accidentally ingested, seek immediate medical attention. Keep calm. NEVER induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
No known acute or delayed effects from exposure to the product.
4.3 Indication of any immediate medical attention and special treatment needed
In case of doubt or when symptoms of feeling unwell persist, get medical attention. Never administer anything orally to persons who are unconscious.
SECTION 5. Firefighting measures
The product is highly inflammable, it can cause or considerably worsen a fire, the necessary prevention measures should be taken and risks avoided. In case of fire, the following measures are recommended:
5.1 Extinguishing media
Recommended extinguishing methods:
Extinguisher powder or CO₂. In case of more serious fires, also alcohol-resistant foam and water spray.
Unsuitable extinguishing media:
Do not use a direct stream of water to extinguish.
5.2 Special hazards arising from the substance or mixture
Special risks:
Fire can cause thick, black smoke. As a result of thermal decomposition, dangerous products can form: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products can be harmful to your health.
5.3 Advice for firefighters
Use water to cool tanks, cisterns, or containers close to the heat source or fire. Take wind direction into account. Prevent the products used to fight the fire from going into drains, sewers, or waterways.
Fire protection equipment:
According to the size of the fire, it may be necessary to use protective suits against the heat, individual breathing equipment, gloves, protective goggles or facemasks and protective footwear.
SECTION 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Eliminate possible ignition points and ventilate the area. Avoid breathing fumes. For exposure control and individual protection measures, see Section 8.
6.2 Environmental precautions
Prevent the contamination of drains, surface or subterranean waters, and the ground.
6.3 Methods and material for containment and cleaning up
Pick up the spill with non-combustible absorbent materials (soil, sand, vermiculite, diatomite, etc.).
Pour the product and the absorbent in an appropriate
container.
6.4 Reference to other sections
For exposure control and individual protection measures, see Section 8.
For later elimination of waste, follow the recommendations under Section 13.
SECTION 7. Handling and storage
7.1 Precautions for safe handling
The fumes are heavier than air and can spread across the ground. They can form explosive mixtures with air. Prevent the creation of flammable or explosive fume concentrations in the air; prevent fume concentrations above work exposure limits. The product must only be used in areas where all unprotected flames and other ignition points have been eliminated.
Electrical equipment has to be protected according to applicable standards. The product can be electrostatically charged: always use earth grounds when transferring the product. Operators must use anti-static footwear and clothing, and floors must be conductors.
Keep the container tightly closed and isolated from heat sources, sparks and fire. Do not use tools that can cause sparks. For personal protection, see Section 8. Never use pressure to empty the containers. They are not pressure-resistant containers.
In the application area, smoking, eating and drinking must be prohibited. Follow legislation on occupational health and safety.
Keep the product in containers made of a material identical to the original.
7.2 Conditions for safe storage, including any incompatibilities
Store according to local legislation. Observe indications on the label. Store the containers between 5 ºC and 35 ºC, in a dry and well-ventilated place, far from sources of heat and direct solar light. Keep far away from ignition points. Keep away from oxidising agents and from highly acidic or alkaline materials. Do not smoke. Prevent the entry of non-authorised persons. Once the containers are open, they must be carefully closed and placed vertically to prevent spills.
The product is not affected by Directive 2012/18/EU (SEVESO III).
7.3 Specific end use(s)
Anti-stain treatment for stone surfaces.
SECTION 8. Exposure controls/personal protection
8.1 Control parameters
Work exposure limits for:
IDENTIFICATION |
COUNTRY |
OCCUPATIONAL EXPOSURE LIMITS |
||
ETHANOL, ETHYL ALCOHOL CAS: 64-17-5 |
United Kingdom(1) |
IOELV (8h) |
1000 ppm |
1920 mg/m3 |
IOELV (STEL) |
– |
– |
||
N-BUTYL ACETATE CAS: 123-86-4 |
United Kingdom(1) |
IOELV (8h) |
150 ppm |
724 mg/m3 |
IOELV (STEL) |
200 ppm |
966 mg/m3 |
||
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL CAS: 67-63-0 |
United Kingdom(1) |
IOELV (8h) |
400 ppm |
999 mg/m3 |
IOELV (STEL) |
500 ppm |
1250 mg/m3 |
(1) According Limit Value (IOELV) list in 2nd Indicative Occupational Exposure adopted by Health and Safety Executive
The product does NOT contain substances with Biological Limit Values
Concentration levels DNEL / DMEL:
IDENTIFICATION |
DNEL / DMEL |
TYPE |
VALUE |
ETHANOL, ETHYL ALCOHOL CAS: 64-17-5 EC: 200-578-6 |
DNEL (Workers) |
Inhalation, Long-term, Systemic effects |
950 mg/m3 |
N-BUTYL ACETATE CAS: 123-86-4 EC: 204-658-1 |
DNEL (Workers) |
Inhalation, Long-term, Systemic effects |
480 mg/m3 |
DNEL (General population) |
Inhalation, Long-term, Systemic effects |
102.34 mg/m3 |
|
DNEL (Workers) |
Inhalation, Acute, Systemic effects |
960 mg/m3 |
|
DNEL (General population) |
Inhalation, Acute, Systemic effects |
859.7 mg/m3 |
|
DNEL (Workers) |
Inhalation, Long-term, Local effects |
480 mg/m3 |
|
DNEL (General population) |
Inhalation, Long-term, Local effects |
102.34 mg/m3 |
|
DNEL (Workers) |
Inhalation, Acute, Local effects |
960 mg/m3 |
|
DNEL (General population) |
Inhalation, Acute, Local effects |
859.7 mg/m3 |
|
DNEL (General population) |
Oral, Long-term, Systemic effects |
3.4 mg/Kg bw/day |
|
DNEL (General population) |
Dermal, Long-term, Systemic effects |
3.4 mg/Kg bw/day |
|
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL CAS: 67-63-0 EC: 200-661-7 |
DNEL (Workers) |
Inhalation, Long-term, Systemic effects |
500 mg/m3 |
DNEL (General population) |
Inhalation, Long-term, Systemic effects |
89 mg/m3 |
|
DNEL (Workers) |
Dermal, Long-term, Systemic effects |
888 mg/Kg bw/day |
|
DNEL (General population) |
Dermal, Long-term, Systemic effects |
319 mg/Kg bw/day |
|
DNEL (General population) |
Oral, Long-term, Systemic effects |
26 mg/Kg bw/day |
DNEL: Derived No Effect Level, level of exposure to the substance below which adverse effects are not anticipated
DMEL: Derived Minimal Effect Level, exposure level corresponding to a low risk, that risk should be considered a tolerable minimum
Concentration levels PNEC:
IDENTIFICATION |
DETAILS |
VALUE |
ETHANOL, ETHYL ALCOHOL CAS: 64-17-5 EC: 200-578-6 |
Fresh water |
0.96 mg/L |
Marine water |
0.79 mg/L |
|
Aqua (Intermittent releases) |
2.75 mg/L |
|
Soil |
0.63 mg/Kg soil dw |
|
Sediment (Freshwater) |
3.6 mg/Kg sediment dw |
|
N-BUTYL ACETATE CAS: 123-86-4 EC: 204-658-1 |
Aqua (Freshwater) |
0.18 mg/L |
Aqua (Marine water) |
0.018 mg/L |
|
Aqua (Intermittent releases) |
0.36 mg/L |
|
PNEC STP |
35.6 mg/L |
|
Sediment (Freshwater) |
0.981 mg/Kg sediment dw |
|
Sediment (Marine water) |
0.0981 mg/Kg sediment dw |
|
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL CAS: 67-63-0 EC: 200-661-7 |
Aqua (Freshwater) |
140.9 mg/L |
Aqua (Marine water) |
140.9 mg/L |
|
Aqua (Intermittent releases) |
140.9 mg/L |
|
Sediment (Freshwater) |
552 mg/Kg sediment dw |
|
Sediment (Marine water) |
552 mg/Kg sediment dw |
|
Soil |
28 mg/Kg soil dw |
|
PNEC STP |
2251 mg/L |
|
PNEC oral (Hazard for predators) |
160 mg/Kg food |
PNEC: Predicted No Effect Concentration, concentration of the substance below which adverse effects are not expected in the environmental compartment
8.2 Exposure controls
Measures of a technical nature:
Provide adequate ventilation, which can be achieved by using good local exhaust-ventilation and a good general exhaust system.
Breathing protection:
If the recommended technical measures are observed, no individual protection equipment is necessary.
Hand protection:
PICTOGRAM |
|
PPE |
Protective gloves against chemicals |
CHARACTERISTICS |
<<CE>> marking, Category III |
CEN STANDARDS |
EN 374-1; EN 374-2; EN 374-3; EN 420 |
MAINTENANCE |
Keep in a dry place, away from any sources of heat, and avoid exposure to sunlight as much as possible. Do not make any changes to the gloves that may alter their resistance, or apply paints, solvents or adhesives. |
OBSERVATIONS |
Gloves should be of the appropriate size and fit the user’s hand well, not being too loose or too tight. Always use with clean, dry hands. |
MATERIAL |
PVC (polyvinyl chloride) |
BREAKTHROUGH TIME |
> 480 min. |
MATERIAL THICKNESS |
0.35 mm |
Eye protection:
PICTOGRAM |
|
PPE |
Protective goggles with built-in frame |
CHARACTERISTICS |
<<CE>> marking, Category II. Eye protector with built-in frame for protection against dust, smoke, fog |
CEN STANDARDS |
EN 165; EN 166; EN 167; EN 168 |
MAINTENANCE |
Visibility through lenses should be ideal. Therefore, these parts should be cleaned daily. Protectors should be disinfected periodically following the manufacturer’s instructions. |
OBSERVATIONS |
Some signs of wear and tear include: yellow colouring of the lenses, superficial scratching of the lenses, scraping, etc. |
Skin protection:
PICTOGRAM |
|
PPE |
Anti-static protective clothing |
CHARACTERISTICS |
<<CE>> marking, Category II. Protective clothing should not be too tight or loose in order not to obstruct the user’s movements |
CEN STANDARDS |
EN 340; EN 1149-1; EN 1149-2; EN 1149-3; EN 1149-5 |
MAINTENANCE |
In order to guarantee uniform protection, follow the washing and maintenance instructions provided by the manufacturer. |
OBSERVATIONS |
The protective clothing should offer a level of comfort in line with the level of protection provided in terms of the hazard against which it protects, bearing in mind environmental conditions, the user’s level of activity and the expected time of use. |
PICTOGRAM |
|
PPE |
Anti-static safety footwear |
CHARACTERISTICS |
<<CE>> marking, Category II |
CEN STANDARDS |
EN ISO 13287; EN ISO 20344; |
MAINTENANCE |
The footwear should be checked regularly. |
OBSERVATIONS |
The level of comfort during use and acceptability are factors that are assessed very differently depending on the user. Therefore, it is advisable to try on different footwear models and, if possible, different widths. |
SECTION 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance: Liquid
Colour: Colourless
Odour: Characteristic
Odour threshold: N.A./N.A.
pH: N.A./N.A.
Melting point: N.A./N.A.
Boiling point: N.A./N.A.
Flash point: 12 ºC
Evaporation rate: N.A./N.A.
Inflammability (solid, gas): N.A./N.A.
Lower explosive limit: N.A./N.A.
Upper explosive limit: N.A./N.A.
Vapour pressure: N.A./N.A.
Vapour density: N.A./N.A.
Relative density: 0.862 ± 0.02 g/cm3
Solubility: Soluble in organic solvents
Liposolubility: N.A./N.A.
Hydrosolubility: Insoluble
Partition coefficient (n-octanol/water): N.A./N.A.
Auto-ignition temperature: N.A./N.A.
Decomposition temperature: N.A./N.A.
Viscosity: N.A./N.A.
Explosive properties: N.A./N.A.
Oxidizing properties: N.A./N.A.
N.A./N.A. = Not Available / Not Applicable due to the nature of the product
9.2 Other information
No data available.
SECTION 10. Stability and reactivity
10.1 Reactivity
The product does not present hazards by their reactivity.
10.2 Chemical stability
Stable under the recommended handling and storage conditions (see Section 7).
10.3 Possibility of hazardous reactions
The product does not present possibility of hazardous reactions.
10.4 Conditions to avoid
Avoid any improper handling.
10.5 Incompatible materials
Keep away from oxidising agents and from highly alkaline or acidic materials in order to prevent exothermic reactions.
10.6 Hazardous decomposition products
No decomposition if used for the intended uses.
SECTION 11. Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Repeated or prolonged contact with the product can cause the elimination of oil form the skin, giving rise to non-allergic contact dermatitis and absorption of the product through the skin.
Splatters in the eyes can cause irritation and reversible damage.
Toxicological information about the substances present in the composition:
IDENTIFICATION |
ACUTE TOXICITY |
|||
TYPE |
TEST |
KIND |
VALUE |
|
ETHANOL, ETHYL ALCOHOL CAS: 64-17-5 EC: 200-578-6 |
Oral |
LD50 |
Rat |
7060 mg/Kg bw(1) |
Dermal |
– |
– |
– |
|
Inhalation |
– |
– |
– |
|
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL CAS: 67-63-0 EC: 200-661-7 |
Oral |
LD50 |
Rat |
5050 mg/Kg bw(2) |
Dermal |
LD50 |
Rabbit |
12800 mg/Kg bw(3) |
|
Inhalation |
– |
– |
– |
(1) Toxicology and Applied Pharmacology. Vol. 16, Pg. 718, 1970
(2) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(1), Pg. 8, 1978
(3) Raw Material Data Handbook, Vol. 1: Organic Solvents, 1974. Vol. 1, Pg. 100, 1974
- Acute toxicity:
Not conclusive data for classification.
- Skin corrosion/irritation:
Product classified:
Skin irritant, Category 2 – Causes skin irritation.
- Serious eye damage/irritation:
Product classified:
Eye irritation, Category 2 – Causes serious eye irritation.
- Respiratory or skin sensitisation:
Not conclusive data for classification.
- Germ cell mutagenicity:
Not conclusive data for classification.
- Carcinogenicity:
Not conclusive data for classification
- Reproductive toxicity:
Not conclusive data for classification
- STOT – single exposure:
Product classified:
Specific target organ toxicity following a single exposure, Category 3. - STOT – repeated exposure:
Not conclusive data for classification.
- Aspiration hazard:
Not conclusive data for classification.
11.2 Information on other hazards
No data available.
SECTION 12. Ecological information
12.1 Toxicity
IDENTIFICATION |
ECOTOXICITY |
|||
TYPE |
TEST |
KIND |
VALUE |
|
ETHANOL, ETHYL ALCOHOL CAS: 64-17-5 EC: 200-578-6 |
Fish |
LC50 |
Fish |
11000 mg/L(1) |
Aquatic invertebrates |
LC50 |
Crustacean |
9280 mg/L(2) |
|
Aquatic plants |
– |
– |
– |
|
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL CAS: 67-63-0 EC: 200-661-7 |
Fish |
LC50 |
Fish |
9640 mg/L(3) |
Aquatic invertebrates |
LC50 |
Crustacean |
1400 mg/L(4) |
|
Aquatic plants |
– |
– |
– |
(1) Bengtsson, B.E., L. Renberg, and M. Tarkpea 1984. Molecular Structure and Aquatic Toxicity – an Example with C1-C13 Aliphatic Alcohols. Chemosphere 13(5/6):613-622
(2) Takahashi, I.T., U.M. Cowgill, and P.G. Murphy 1987. Comparison of Ethanol Toxicity to Daphnia magna and Ceriodaphnia dubia Tested at Two Different Temperatures: Static Acute Toxicity Test Results. Bull.Environ.Contam.Toxicol. 39(2):229-236. Ziegenfuss, P.S., W.J. Renaudette, and W.J. Adams 1986. Methodology for Assessing the Acute Toxicity of Chemicals Sorbed to Sediments: Testing the Equilibrium Partitioning Theory. In: T.M. Poston and R. Purdy (Eds.), Aquatic Toxicology and Environmental Fate, 9th Volume, ASTM STP 921, Philadelphia, PA: 479-493
(3) Brooke, L.T., D.J. Call, D.L. Geiger, and C.E. Northcott 1984. Acute Toxicities of Organic Chemicals to Fathead Minnows (Pimephales promelas), Vol. 1. Center for Lake Superior Environmental Stud., Univ. of Wisconsin-Superior, Superior, WI: 414
(4) Blackman, R.A.A. 1974. Toxicity of Oil-Sinking Agents. Mar. Pollut. Bull. 5: 116-118
12.2 Persistence and degradability
No information is available about persistence and degradability of the product.
12.3 Bioaccumulative potential
Information about the bioaccumulation of the substances present:
IDENTIFICATION |
BIOACCUMULATION |
|||
LOG POW |
BCF |
NOECs |
LEVEL |
|
ETHANOL, ETHYL ALCOHOL CAS: 64-17-5 EC: 200-578-6 |
– 0.3 |
– |
– |
Very low |
N-BUTYL ACETATE CAS: 123-86-4 EC: 204-658-1 |
1.78 |
– |
– |
Very low |
ISOPROPANOL, ISOPROPYL ALCOHOL, PROPAN-2-OL CAS: 67-63-0 EC: 200-661-7 |
0.05 |
– |
– |
Very low |
12.4 Mobility in soil
No information is available about the mobility in soil. The product must not be allowed to go into sewers or waterways.
Prevent penetration into the ground.
12.5 Results of PBT and vPvB assessment
No information is available about the results of PBT and vPvB assessment of the product.
12.6 Endocrine disrupting properties
No data available.
12.7 Other adverse effects
No data available.
SECTION 13. Disposal considerations
13.1 Waste treatment methods
Do not dump into sewers or waterways. Waste and empty containers must be handled and eliminated according to current, local/national legislation.
Follow the provisions of Directive 2008/98/EC
regarding waste management.
SECTION 14. Transport information
Transport following ADR rules for road transport, RID rules for railway, ADN for inner waterways, IMDG for sea and ICAO/IATA for air transport.
Land: Transport by road: ADR, Transport by rail: RID.
Transport documentation: Consignment note and written instructions.
Sea: Transport by ship: IMDG.
Transport documentation: Bill of lading.
Air: Transport by plane: ICAO/IATA.
Transport document: Airway bill.
14.1 UN number or ID number
UN No: UN1993.
14.2 UN proper shipping name
Description: UN 1993, FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ETHYL ALCOHOL / TRIETOXI(METIL)SILANO), 3, PG II, (D/E).
14.3 Transport hazard class(es)
Class(es): 3.
14.4 Packing group
Packing group: II.
14.5 Environmental hazards
Marine pollutant: No.
14.6 Special precautions for user
Labels: 3
Hazard number: 33
ADR LQ: 1 L
Provisions concerning carriage in bulk ADR: Not authorized carriage in bulk in accordance with ADR.
Transport by ship, FEm – Emergency sheets (F- Fire, S – Spills): F-E, S-E. Proceed in accordance with point 6.
14.7 Maritime transport in bulk according to IMO instruments
The product is not transported in bulk.
SECTION 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The product is not affected by the Regulation (EC) No 1005/2009 of the European Parliament and of the Council of 16 September 2009 on substances that deplete the ozone layer.
See Annex I of the Directive 96/82/EC of 9 December 1996 on the control of major-accident hazards involving dangerous substances and the Regulation (EC) No 689/2008 of the European Parliament and of the council of 17 June 2008 concerning the export and import of dangerous chemicals and its subsequent updates.
The product is not affected by Directive 2012/18/EU (SEVESO III).
The product is not affected by Regulation (EU) No 528/2012 concerning the making available on the market and use of biocidal products.
The product is not affected by the procedure established Regulation (EU) No 649/2012, concerning the export and import of dangerous chemicals.
15.2 Chemical safety assessment
There has been no evaluation a chemical safety assessment of the product.
SECTION 16. Other information
Sections modified from the previous version:
All the headings are modified due to the update of the safety datasheet to the requirements of Regulation (EU) 1272/2008 and Regulation (EU) 2020/878. This version of the SDS replaces all previous versions.
It is recommended that the product only be employed for the purposes advised.
Complete text of the H phrases that appear in Section 3:
H224: Extremely flammable liquid and vapour.
H225: Highly flammable liquid and vapour.
H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
EUH066: Repeated exposure may cause skin dryness or cracking.
Classification codes:
Eye Irrit. 2 – Eye irritation, Category 2
Flam. Liq. 1 – Flammable liquid, Category 1
Flam. Liq. 2 – Flammable liquid, Category 2
Flam. Liq. 3 – Flammable liquid, Category 3
STOT SE 3 – Specific target organ toxicity following a single exposure, Category 3
Skin Irrit. 2 – Skin irritant, Category 2
Abbreviations and acronyms used:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
BCF: Bioconcentration factor
CEN: European Committee for Standardization
DMEL: Derived Minimal Effect Level, exposure level corresponding to a low risk, that risk should be considered a tolerable minimum
DNEL: Derived No Effect Level, level of exposure to the substance below which adverse effects are not anticipated
EC50: Half maximal effective concentration
PPE: Personal protection equipment
IATA: International Air Transport Association
IMDG: International Maritime Code for Dangerous Goods
LC50: Lethal concentration, 50 %
LD50: Lethal dose, 50 %
Log Pow: Logarithm of the partition octanol-water
NOEC: No Observed Effect Concentration
PNEC: Predicted No Effect Concentration, concentration of the substance below which adverse effects are not expected in the environmental compartment
RID: Regulations concerning the International Transport of Dangerous Goods by Rail
Key literature references and sources for data:
- http://eur-lex.europa.eu/homepage.html
- http://echa.europa.eu/
- Regulation (EU) 2015/830
- Regulation (EC) No 1907/2006
- Regulation (EU) No 1272/2008
The information given in the Safety Datasheet has been drafted in accordance with REGULATION (EU) 2020/878 OF THE COMMISSION of June 18, 2020 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.
The information in this Safety Datasheet on the Preparation is based on current knowledge and on current EC and national laws, as far as the working conditions of the users is beyond our knowledge and control. The product must not be used for purposes other than those that are specified without first having written instructions on how to handle. It is always the responsibility of the user to take the appropriate measures in order to comply with the requirements established by current legislation. The information contained in this Safety Sheet only states a description of the safety requirements for the preparation, and it must not be considered as a guarantee of its properties.