SAFETY DATASHEET
SOLUMASTIK
REV. 02 – 02/2022
PRINT DATE 02/2022
According to COMMISSION REGULATION (EU) 2020/878
Note on the translation: An automatic machine translation of this document is made possible in this page, while a human translation is prepared. Use the contact form if you wish to receive a human translation of this document.
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
SOLUMASTIK
Other means of identification:
Non-applicable.
UFI:
D300-E007-X00W-GYPH
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant uses:
Adhesive for marble and artificial stone. For professional users/industrial user only.
Uses advised against:
All uses not specified in this section or in section 7.3.
1.3 Details of the manufacturer/supplier of the safety data sheet
Manufacturer:
Tecnología de Polímeros QMC, S.L.U.
C/Ausias March, Parcela 13 A
Pol. Ind. La Pobla – La Eliana
46185 La Pobla de Vallbona (Valencia) – Spain
Phone: +34 962 725 676 – Fax: +34 962 740 906
E-mail: info@qmc.es
Website: www.qmc.es
Supplier:
Cosentino Global S.L.U.,
Ctra. A334, Baza-Huércal Overa, km 59
04850 Cantoria (Almería) – Spain
Phone: +34 950 444 175
E-mail: info@cosentino.com
Website: www.cosentino.com
1.4 Emergency telephone number
ChemTel Inc. (24/7/365, multilingual):
Worldwide: +1-813-248-0585
United States: 1-800-255-3924 (free toll)
Australia: 1-300-954-583
China: 400-120-0751
India: 000-800-100-4086
Mexico: 01-800-099-0731
Brazil: 0-800-591-6042
For information on emergency phone numbers of EU national authorities you may check:
SECTION 2. Hazards identification
2.1 Classification of the substance or mixture
CLP Regulation (EC) No 1272/2008
Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008.
Eye Irrit. 2: Eye irritation, Category 2, H319
Flam. Liq. 3: Flammable liquids, Category 3, H226
Repr. 2: Reproductive toxicity, Category 2, H361d
Skin Irrit. 2: Skin irritation, Category 2, H315
Skin Sens. 1A: Sensitisation, skin, Category 1A, H317
STOT RE 1: Specific target organ toxicity – Repeated exposure, Hazard Category 1, H372
2.2 Label elements
CLP Regulation (EC) No 1272/2008:
Danger
Hazard statements:
Eye Irrit. 2: H319 – Causes serious eye irritation.
Flam. Liq. 3: H226 – Flammable liquid and vapour.
Repr. 2: H361d – Suspected of damaging the unborn child.
Skin Irrit. 2: H315 – Causes skin irritation.
Skin Sens. 1A: H317 – May cause an allergic skin reaction.
STOT RE 1: H372 – Causes damage to organs through prolonged or repeated exposure.
Precautionary statements:
P201: Obtain special instructions before use.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear.
P302+P352: IF ON SKIN: Wash with plenty of water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P370+P378: In case of fire: Use ABC powder extinguisher to extinguish.
P501: Dispose of contents/container in accordance with regulations on hazardous waste or packaging and packaging waste respectively.
Substances that contribute to the classification:
STYRENE; MALEIC ANHYDRIDE.
2.3 Other hazards
Product fails to meet PBT/vPvB criteria.
Endocrine-disrupting properties: The product fails to meet the criteria.
SECTION 3. Composition / information on ingredients
3.1 Substance
Non-applicable.
3.2 Mixture
Chemical description:
Mixture composed of additives, pigments and resins.
Components:
In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains:
IDENTIFICATION |
CHEMICAL NAME/CLASSIFICATION |
CONCENTRATION |
|||
CAS: |
100-42-5 |
Styrene(1) |
ATP ATP06 |
10 % – < 18 % |
|
EC: |
202-851-5 |
Regulation 1272/2008 |
Acute Tox. 4: H332; Eye Irrit. 2: H319; |
|
|
Index: |
601-026-00-0 |
||||
REACH: |
01-2119457861-32-XXXX |
||||
CAS: |
67-56-1 |
Methanol(1) |
ATP CLP00 |
0.1 % – < 1 % |
|
EC: |
200-659-6 |
Regulation 1272/2008 |
Acute Tox. 3: H301+H311+H331; |
|
|
Index: |
603-001-00-X |
||||
REACH: |
01-2119433307-44-XXXX |
||||
CAS: |
108-31-6 |
Maleic anhydride(1) |
ATP ATP13 |
< 0.1 % |
|
EC: |
203-571-6 |
Regulation 1272/2008 |
Acute Tox. 4: H302; Eye Dam. 1: H318; |
|
|
Index: |
607-096-00-9 |
||||
REACH: |
01-2119472428-31-XXXX |
(1) Substances presenting a health or environmental hazard which meet criteria laid down in Regulation (EU) No 2020/878
To obtain more information on the hazards of the substances consult sections 11, 12 and 16.
Other information:
IDENTIFICATION |
SPECIFIC CONCENTRATION LIMIT |
Methanol |
% (p/p) > = 10: STOT SE 1 – H370 3 < = % (p/p) < 10: STOT SE 2 - H371 |
CAS: 67-56-1 |
|
EC: 200-659-6 |
|
Maleic anhydride |
% (p/p) > = 0.001: Skin Sens. 1A – H317 |
CAS: 108-31-6 |
|
EC: 203-571-6 |
SECTION 4. First aid measures
4.1 Description of first measures
The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medial attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product.
By inhalation:
Remove the person affected from the area of exposure, provide with fresh air and keep at rest. In serious cases such as cardiorespiratory failure, artificial resuscitation techniques will be necessary (mouth to mouth resuscitation, cardiac massage, oxygen supply, etc.) requiring immediate medical assistance.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection.
By eye contact:
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, in which case this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product.
By ingestion/aspiration:
Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion.
4.2 Most important symptoms and effects, both acute and delayed
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed
Non-applicable.
SECTION 5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media:
If possible use polyvalent powder fire extinguishers (ABC powder), alternatively use foam or carbon dioxide extinguishers (CO₂).
Unsuitable extinguishing media:
IT IS RECOMMENDED NOT to use full jet water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk.
5.3 Advice for firefighters
Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus (SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit, …) in accordance with Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.
SECTION 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel:
Isolate leaks provided that there is no additional risk for the people performing this task. Evacuate the area and keep out those without protection. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Above all prevent the formation of any vapour-air flammable mixtures, through either ventilation or the use of an inert medium. Destroy any source of ignition. Eliminate electrostatic charges by interconnecting all the conductive surfaces on which static electricity could form, and also ensuring that all surfaces are connected to the ground.
For emergency responders:
See section 8.
6.2 Environmental precautions
This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water.
6.3 Methods and material for containment and cleaning up
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbers. For any concern related to disposal consult section 13.
6.4 Reference to other sections
See sections 8 and 13.
SECTION 7. Handling and storage
7.1 Precautions for safe handling
Precautions for safe manipulation:
Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used.
Technical recommendations for the prevention of fires and explosions:
Transfer in well ventilated areas, preferably through localized extraction. Fully control sources of ignition (mobile phones, sparks, …) and ventilate during cleaning operations. Avoid the existence of dangerous atmospheres inside containers, applying inertization systems where possible. Transfer at a slow speed to avoid the creation of electrostatic charges. Against the possibility of electrostatic charges: ensure a perfect equipotential connection, always use groundings, do not wear work clothes made of acrylic fibres, preferably wearing cotton clothing and conductive footwear. Comply with the essential security requirements for equipment and systems defined in Directive 2014/34/EC (ATEX 100) and with the minimum requirements for protecting the security and health of workers under the selection criteria of Directive 1999/92/EC (ATEX 137). Consult section 10 for conditions and materials that should be avoided.
Technical recommendations to prevent ergonomic and toxicological risks:
PREGNANT WOMEN SHOULD NOT BE EXPOSED TO THIS PRODUCT. Transfer in designated areas that comply with the necessary safety conditions (emergency showers and eyewash stations in close proximity), using personal protection equipment, especially on the hands and face (See section 8). Limit manual transfers to small amounts only. Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
Technical recommendations to prevent environmental risks:
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3).
7.2 Conditions for safe storage, including any incompatibilities
Technical measures for storage:
Minimum Temp.: 5 ºC
Maximum Temp.: 30 ºC
Maximum time: 12 Months
General conditions for storage:
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5.
7.3 Specific end use(s)
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.
SECTION 8. Exposure controls / personal protection
8.1 Control parameters
Substances whose occupational exposure limits have to be monitored in the workplace (European OEL, not country-specific legislation):
Directive (EU) 2000/39, Directive 2004/37/EC, Directive (EU) 2006/15, Directive (EU) 2009/161, Directive (EU) 2017/164, Directive (EU) 2019/1831:
IDENTIFICATION |
OCCUPATIONAL EXPOSURE LIMITS |
||
Methanol |
IOELV (8h) |
200 ppm |
260 mg/m3 |
CAS: 67-56-1 EC: 200-659-6 |
IOELV (STEL) |
– |
– |
DNEL (Workers):
IDENTIFICATION |
SHORT EXPOSURE |
LONG EXPOSURE |
|||
SYSTEMIC |
LOCAL |
SYSTEMIC |
LOCAL |
||
Styrene |
Oral |
Non-applicable |
Non-applicable |
Non-applicable |
Non-applicable |
CAS: 100-42-5 |
Dermal |
Non-applicable |
Non-applicable |
406 mg/kg |
Non-applicable |
EC: 202-851-5 |
Inhalation |
289 mg/m3 |
306 mg/m3 |
85 mg/m3 |
Non-applicable |
Methanol |
Oral |
Non-applicable |
Non-applicable |
Non-applicable |
Non-applicable |
CAS: 67-56-1 |
Dermal |
20 mg/kg |
Non-applicable |
20 mg/kg |
Non-applicable |
EC: 200-659-6 |
Inhalation |
130 mg/m3 |
130 mg/m3 |
130 mg/m3 |
130 mg/m3 |
Maleic anhydride |
Oral |
Non-applicable |
Non-applicable |
Non-applicable |
Non-applicable |
CAS: 108-31-6 |
Dermal |
Non-applicable |
Non-applicable |
Non-applicable |
Non-applicable |
EC: 203-571-6 |
Inhalation |
0.2 mg/m3 |
0.2 mg/m3 |
0.081 mg/m3 |
0.081 mg/m3 |
DNEL (General population):
IDENTIFICATION |
SHORT EXPOSURE |
LONG EXPOSURE |
|||
SYSTEMIC |
LOCAL |
SYSTEMIC |
LOCAL |
||
Styrene |
Oral |
Non-applicable |
Non-applicable |
2.1 mg/kg |
Non-applicable |
CAS: 100-42-5 |
Dermal |
Non-applicable |
Non-applicable |
343 mg/kg |
Non-applicable |
EC: 202-851-5 |
Inhalation |
174.25 mg/m3 |
182.75 mg/m3 |
10.2 mg/m3 |
Non-applicable |
Methanol |
Oral |
4 mg/kg |
Non-applicable |
4 mg/kg |
Non-applicable |
CAS: 67-56-1 |
Dermal |
4 mg/kg |
Non-applicable |
4 mg/kg |
Non-applicable |
EC: 200-659-6 |
Inhalation |
26 mg/m3 |
26 mg/m3 |
26 mg/m3 |
26 mg/m3 |
PNEC:
IDENTIFICATION |
||||
Styrene |
STP |
5 mg/L |
Fresh water |
0.028 mg/L |
CAS: 100-42-5 |
Soil |
0.2 mg/kg |
Marine water |
0.014 mg/L |
EC: 202-851-5 |
Intermittent |
0.04 mg/L |
Sediment (Fresh water) |
0.614 mg/kg |
Oral |
Non-applicable |
Sediment (Marine water) |
0.307 mg/kg |
|
Methanol |
STP |
100 mg/L |
Fresh water |
20.8 mg/L |
CAS: 67-56-1 |
Soil |
100 mg/kg |
Marine water |
2.08 mg/L |
EC: 200-659-6 |
Intermittent |
1540 mg/L |
Sediment (Fresh water) |
77 mg/kg |
Oral |
Non-applicable |
Sediment (Marine water) |
7.7 mg/kg |
|
Maleic anhydride |
STP |
44.6 mg/L |
Fresh water |
0.038 mg/L |
CAS: 108-31-6 |
Soil |
0.037 mg/kg |
Marine water |
0.004 mg/L |
EC: 203-571-6 |
Intermittent |
0.379 mg/L |
Sediment (Fresh water) |
0.296 mg/kg |
Oral |
Non-applicable |
Sediment (Marine water) | 0.03 mg/kg |
8.2 Exposure controls
Individual protection measures, such as personal protective equipment:
In accordance with the order of importance to control professional exposure (Directive 98/24/EC) it is recommended to use localized extraction in the work area as a collective protection measure to avoid exceeding the occupational exposure limits. In case of using personal protective equipment it should have CE marking in accordance with Directive 2016/425/EC. For more information on Personal Protective Equipment (storage, use, cleaning, maintenance, class of protection, …) consult the information leaflet provided by the manufacturer. For additional information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal.
Respiratory protection:
PICTOGRAM |
PPE |
LABELLING |
CEN STANDARD |
REMARKS |
Mandatory respiratory tract protection |
Filter mask for gases and vapours |
|
EN 405:2002+A1:2010 |
Replace when there is a taste or smell of the contaminant inside the face mask. If the contaminant comes with warnings it is recommended to use isolation equipment. |
Specific protection for the hands:
PICTOGRAM |
PPE |
LABELLING |
CEN STANDARD |
REMARKS |
Mandatory hand protection |
Chemical protective gloves (Material: Linear low-density polyethylene (LLDPE), Breakthrough time: > 480 min, Thickness: 0.062 mm) |
|
EN 420:2004+A1:2010 |
Replace the gloves at any sign of deterioration. |
As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application.
Ocular and facial protection:
PICTOGRAM |
PPE |
LABELLING |
CEN STANDARD |
REMARKS |
Mandatory face protection |
Face shield |
|
EN 166:2002 EN 167:2002 EN 168:2002 EN ISO 4007:2018 |
Clean daily and disinfect periodically according to the manufacturer’s instructions. Use if there is a risk of splashing. |
Body protection:
PICTOGRAM |
PPE |
LABELLING |
CEN STANDARD |
REMARKS |
Mandatory complete body protection |
Disposable clothing for protection against chemical risks, with antistatic and fireproof properties |
|
EN 1149-1, 2, 3 EN 13034:2005+A1:2009 EN ISO 13982-A:2004/A1:2010 EN ISO 6529:2013 EN ISO 6530:2005 EN ISO 13688:2013 EN 464:1994 |
For professional use only. Clean periodically according to the manufacturer’s instructions. |
Mandatory foot protection |
Safety footwear for protection against chemical risk, with antistatic and heat resistant properties |
|
EN ISO 13287:2013 EN ISO 20345:2011 EN 13832-1:2019 |
Replace boots at any sign of deterioration. |
Additional emergency measures:
EMERGENCY MEASURE |
STANDARDS |
EMERGENCY MEASURE |
STANDARDS |
Emergency shower |
ANSI Z358-1 ISO 3864-1:2011 ISO 3864-4:2011 |
Eyewash stations |
DIN 12 899 ISO 3864-1:2011 ISO 3864-4:2011 |
Environmental exposure controls:
In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D.
SECTION 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
For complete information, see the product data sheet.
Appearance:
Physical state at 20 ºC: Liquid
Appearance: Viscous
Colour: According to the markings on the package
Odour: Characteristic
Odour threshold: Non-applicable *
Volatility:
Boiling point at atmospheric pressure: 140 ºC
Vapour pressure at 20 ºC: 1825 Pa
Vapour pressure at 50 ºC: 8411.61 Pa (8.41 kPa)
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: Non-applicable *
Relative density at 20 ºC: 1.4 – 1.6
Dynamic viscosity at 20 ºC: 22000 – 28000 cP
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: > 20.5 mm2/s
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility properties: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: 30 ºC
Flammability (solid, gas): Non-applicable *
Autoignition temperature: 464 ºC
Lower flammability limit: Not available
Upper flammability limit: Not available
Particle characteristics:
Median equivalent diameter: Non-applicable
9.2 Other information
Information with regard to physical hazard classes:
Explosive properties: Non-applicable *
Oxidising properties: Non-applicable *
Corrosive to metals: Non-applicable *
Heat of combustion: Non-applicable *
Aerosols-total percentage (by mass) of flammable components: Non-applicable *
Other safety characteristics:
Surface tension at 20 ºC:Non-applicable *
Refraction index:Non-applicable *
* Not relevant due to the nature of the product, not providing information property of its hazards
SECTION 10. Stability and reactivity
10.1 Reactivity
No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7.
10.2 Chemical stability
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid
Applicable for handling and storage at room temperature:
Shock and friction: Not applicable
Contact with air: Not applicable
Increase in temperature: Risk of combustion
Sunlight: Avoid direct impact
Humidity: Not applicable
10.5 Incompatible materials
Acids: Avoid strong acids
Water: Not applicable
Oxidising materials: Avoid direct impact
Combustible materials: Not applicable
Others: Avoid alkalis or strong bases
10.6 Hazardous decomposition products
See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds.
SECTION 11. Toxicological information
1.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
The experimental information related to the toxicological properties of the product itself is not available.
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits, adverse effects on health may result, depending on the means of exposure:
Ingestion (acute effect):
- Acute toxicity: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for consumption. For more information see section 3.
- Corrosivity/Irritability: The consumption of a considerable dose can cause irritation in the throat, abdominal pain, nausea and vomiting.
Inhalation (acute effect):
- Acute toxicity: Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous for inhalation. For more information see section 3.
- Corrosivity/Irritability: Prolonged inhalation of the product is corrosive to mucous membranes and the upper respiratory tract.
Contact with the skin and the eyes (acute effect):
- Contact with the skin: Produces skin inflammation.
- Contact with the eyes: Produces eye damage after contact.
CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the effects mentioned. For more information see section 3.IARC: Talc (3); Styrene (2A)
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
- Reproductive toxicity: Suspected of damaging the unborn child.
Sensitizing effects:
- Respiratory: Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous with sensitising effects. For more information see section 3.
- Cutaneous: Prolonged contact with the skin can result in episodes of allergic contact dermatitis.
Specific target organ toxicity (STOT) – single exposure:
- Based on available data, the classification criteria are not met. However, it does contain substances which are classified as dangerous as a result of a single exposure. For more information see section 3.
Specific target organ toxicity (STOT) – repeated exposure:
- Specific target organ toxicity (STOT) – repeated exposure: Serious health effects in the case of prolonged consumption, including death, serious functional disorders or morphological changes of toxicological importance.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
Aspiration hazard:
- Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
Other information:
Non-applicable.
Specific toxicology information on the substances:
100-42-5 Styrene |
Acute toxicity |
Genus |
LD50 oral |
> 2000 mg/kg |
– |
LD50 dermal |
> 2000 mg/kg |
– |
LC50 inhalation |
12 mg/L (4 h) |
Rat |
67-56-1 Methanol |
Acute toxicity |
Genus |
LD50 oral |
100 mg/kg |
Rat |
LD50 dermal |
300 mg/kg |
Rabbit |
LC50 inhalation |
3 mg/L (4 h) |
Rat |
108-31-6 |
Acute toxicity |
Genus |
LD50 oral |
> 2000 mg/kg |
– |
LD50 dermal |
> 2000 mg/kg |
– |
LC50 inhalation |
> 5 mg/L |
– |
11.2 Information on other hazards
Endocrine disrupting properties:
Endocrine-disrupting properties: The product fails to meet the criteria.
Other information:
Non-applicable.
SECTION 12. Ecological information
The experimental information related to the eco-toxicological properties of the product itself is not available.
12.1 Toxicity
Acute toxicity:
Methanol | CAS: 67-56-1 | EC: 200-659-6 |
|||
Concentration |
Species |
Genus |
|
LC50 |
15400 mg/L (96 h) |
Lepomis macrochirus |
Fish |
EC50 |
12000 mg/L (96 h) |
Nitrocra spinipes |
Crustacean |
EC50 |
530 mg/L (168 h) |
Microcystis aeruginosa |
Algae |
Chronic toxicity:
Methanol | CAS: 67-56-1 | EC: 200-659-6 |
|||
Concentration |
Species |
Genus |
|
NOEC |
15800 mg/L |
Oryzias latipes |
Fish |
NOEC |
122 mg/L |
Daphnia magna |
Crustacean |
12.2 Persistence and degradability
Methanol | CAS: 67-56-1 | EC: 200-659-6 |
|||
Degradability |
Biodegradability |
||
BOD5 |
Non-applicable |
Concentration |
100 mg/L |
COD |
1.42 g O2/g |
Period |
14 days |
BOD5/COD |
Non-applicable |
% Biodegradable |
92 % |
12.3 Bioaccumulative potential
Methanol | CAS: 67-56-1 | EC: 200-659-6 |
|
Bioaccumulation potential |
|
BCF |
3 |
Pow Log |
– 0.77 |
Potential |
Low |
12.4 Mobility in soil
Styrene | CAS: 100-42-5 | EC: 202-851-5 |
|||
Absorption/desorption |
Volatility |
||
Koc |
Non-applicable |
Henry |
Non-applicable |
Conclusion |
Non-applicable |
Dry soil |
Non-applicable |
Surface |
3.21E-2 N/m (25 ºC) |
Moist soil |
Non-applicable |
Methanol | CAS: 67-56-1 | EC: 200-659-6 |
|||
Absorption/desorption |
Volatility |
||
Koc |
Non-applicable |
Henry |
Non-applicable |
Conclusion |
Non-applicable |
Dry soil |
Non-applicable |
Surface |
2.355E-2 |
Moist soil |
Non-applicable |
Maleic anhydride | CAS: 108-31-6 | EC: 203-571-6 |
|||
Absorption/desorption |
Volatility |
||
Koc |
Non-applicable |
Henry |
Non-applicable |
Conclusion |
Non-applicable |
Dry soil |
Non-applicable |
Surface |
1.673E-2 |
Moist soil |
Non-applicable |
12.5 Results of PBT and vPvB assessment
Product fails to meet PBT/vPvB criteria.
12.6 Endocrine disrupting properties
Endocrine-disrupting properties: The product fails to meet the criteria.
12.7 Other adverse effects
Not described.
SECTION 13. Disposal considerations
13.1 Waste treatment methods
Code: 08 04 09*
Description: Waste adhesives and sealants containing organic solvents or other hazardous substances
Waste class (Regulation (EU) No 1357/2014): Dangerous
Type of waste (Regulation (EU) No 1357/2014):
HP3 Flammable, HP5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity, HP10 Toxic for reproduction, HP4 Irritant – skin irritation and eye damage.
Waste management (disposal and evaluation): Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to waste management are stated.
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014.
SECTION 14. Transport information
Transport of dangerous goods by land:
With regard to ADR 2021 and RID 2021:
14.1 UN number or ID number
UN1866
14.2 UN proper shipping name
RESIN SOLUTION, flammable
14.3 Transport hazard class(es)
3; Labels: 3
14.4 Packing group
III
14.5 Environmental hazards
No
14.6 Special precautions for user
Special regulations: Non-applicable
Tunnel restriction code: D/E
Physio-Chemical properties: See section 9
Limited quantities: 5 L
14.7 Maritime transport in bulk according to IMO instruments
Non-applicable
Note: Not applicable in receptacles of less than 450 litres (2.2.3.1.5)
Transport of dangerous goods by sea:
With regard to IMDG 39-18:
14.1 UN number or ID number
UN1866
14.2 UN proper shipping name
RESIN SOLUTION, flammable
14.3 Transport hazard class(es)
3; Labels: 3
14.4 Packing group
III
14.5 Marine pollutant
No
14.6 Special precautions for user
Special regulations: 955, 223
EmS Codes: F-E, S-E
Physio-Chemical properties: See section 9
Limited quantities: 5 L
Segregation group: Non-applicable
14.7 Maritime transport in bulk according to IMO instruments
Non-applicable
Note: Not applicable in receptacles of less than 30 litres (2.3.2.5)
Transport of dangerous goods by air:
With regard to IATA/ICAO 2021:
14.1 UN number or ID number
UN1866
14.2 UN proper shipping name
RESIN SOLUTION, flammable
14.3 Transport hazard class(es)
3; Labels: 3
14.4 Packing group
III
14.5 Environmental hazards
No
14.6 Special precautions for user
Physio-Chemical properties: See section 9
14.7 Maritime transport in bulk according to IMO instruments
Non-applicable
SECTION 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable
Substances included in Annex XIV of REACH (“Authorisation List”) and sunset date: Non-applicable
Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable
Article 95, REGULATION (EU) No 528/2012:
Non-applicable
REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Seveso III:
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH, etc …):
Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects.
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this product.
Other legislation:
The product could be affected by sectorial legislation.
15.2 Chemical safety assessment
The supplier has not carried out evaluation of chemical safety.
SECTION 16. Other information
Legislation related to safety data sheets:
The SDS shall be supplied in an official language of the country where the product is places on the market. This safety data sheet has been designed in accordance with ANNEX II – Guide to the compilation of safety data sheets of Regulation (EC) No 1907/2006 (COMMISSION REGULATION (EU) 2020/878).
Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks:
COMMISSION REGULATION (EU) 2020/878
COMPOSITION/INFORMATION ON INGREDIENTS (SECTION 3, SECTION 11, SECTION 12):
- New declared substances
Styrene (100-42-5) - Removed substances
Styrene (100-42-5)
Substances that contribute to the classification (SECTION 2):
- New declared substances
Styrene (100-42-5) - Removed substances
Styrene (100-42-5)
CLP Regulation (EC) No 1272/2008 (SECTION 2, SECTION 16):
- Hazard statements
Texts of the legislative phrases mentioned in section 2:
H315: Causes skin irritation.
H372: Causes damage to organs through prolonged or repeated exposure.
H361d: Suspected of damaging the unborn child.
H317: May cause an allergic skin reaction.
H226: Flammable liquid and vapour.
H319: Causes serious eye irritation.
Texts of the legislative phrases mentioned in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3.
CLP Regulation (EC) No 1272/2008:
Acute Tox. 3: H301+H311+331 – Toxic if swallowed, in contact with skin or if inhaled.
Acute Tox. 4: H302 – Harmful if swallowed.
Acute Tox. 4: H332 – Harmful if inhaled.
Eye Dam. 1: H318 – Causes serious eye damage.
Eye Irrit. 2: H319 – Causes serious eye irritation.
Flam. Liq. 2: H225 – Highly flammable liquid and vapour.
Flam. Liq. 3: H226 – Flammable liquid and vapour.
Repr. 2: H361d – Suspected of damaging the unborn child.
Resp. Sens. 1: H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin Corr. 1B: H314 – Causes severe skin burns and eye damage.
Skin Irrit. 2: H315 – Causes skin irritation.
Skin Sens. 1A: H317 – May cause an allergic skin reaction.
STOT RE 1: H372 – Causes damage to organs through prolonged or repeated exposure (Inhalation).
STOT RE 1: H372 – Causes damage to organs through prolonged or repeated exposure.
STOT SE 1: H370 – Causes damage to organs.
Classification procedure:
Skin Irrit. 2: Calculation method
STOT RE 1: Calculation method
Repr. 2: Calculation method
Skin Sens. 1A: Calculation method
Flam. Liq. 3: Calculation method (2.6.4.3)
Eye Irrit. 2: Calculation method
Advice related to training:
Minimal training is recommended in order to prevent industrial risk for staff using this product and to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
Abbreviations and acronyms:
- ADR: European agreement concerning the international carriage of dangerous goods by road
- IMDG: International maritime dangerous goods code
- IATA: International Air Transport Association
- ICAO: International Civil Aviation Organisation
- COD: Chemical Oxygen Demand
- BOD5: 5day biochemical oxygen demand
- BCF: Bioconcentration factor
- LD50: Lethal Dose 50
- LC50: Lethal Concentration 50
- EC50: Effective Concentration 50
- LogPOW: Octanolwater partition coefficient
- Koc: Partition coefficient of organic carbon
- UFI: Unique Formula Identifier
- IARC: International Agency for Research on Cancer